RESEARCH ARTICLE

 

Physicochemical properties of porous activated carbon prepared from palm kernel shell through a low-cost activation protocol

 

 

Aloysius A. Pam^I; Abdul H. Abdullah^{II, III}; Yen P. Tan^II; Zulkarnain Zainal^II

^IChemistry Department, Federal University Lokoja, Lokoja, Nigeria
^IIChemistry Department, University of Putra Malaysia, Selangor, Malaysia
^IIIMaterial Synthesis and Characterisation Laboratory, Institute of Advanced Technology, University of Putra Malaysia, Selangor, Malaysia

Correspondence

 

 

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ABSTRACT

Biomass-promoting routes for the synthesis of activated carbon (AC) have recently received considerable attention due to the advantages of this method: it is simple, cost-effective, and ecofriendly. This method is also an alternative way to avoid the unsafe practice of waste incineration. We describe the preparation of activated carbon from palm kernel shell (PKS) - an abundant biomass that is available in Africa and Asia. We investigated the effect of process variables such as impregnation ratio (ratio of H₃PO₄ to PKS) and carbonisation temperature (500-700 °C) on yield, microstructure, morphology, pore structure, and adsorption properties to optimise these parameters. Nitrogen adsorption isotherm analysis indicated that the AC was predominantly microporous in nature. Under optimal conditions, an AC with the highest surface area of 1560 m²/g was obtained. The aqueous adsorption test showed that the AC had significant removal capacity for methylene blue and iodine. The higher iodine value is consistent with the structural properties of the adsorbent, while the lower methylene blue value is consistent with the limited mesopore width. Considering the chemical and surface properties and adsorption properties of the AC produced, PKS has been shown to be an excellent precursor material for AC, thus solving the disposal problems associated with this biomass.
SIGNIFICANCE: •AC significantly promotes adsorption and offers a low-cost and cleaner production method. •PKS could serve as a dependable precursor for the synthesis of porous AC. •This study provides useful information on how H₃PO₄-impregnated PKS influences the porosity of the resulting AC. •Differences in porosity, yield, and morphology and Brunauer-Emmet-Teller surface area are achievable using AC from PKS

Keywords: activated carbon, palm kernel shell, H₃PO₄ ratio, biomass, pyrolysis, ecofriendly

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Introduction

Activated carbon (AC) is an excellent adsorbent with good physical and chemical properties, including a large surface area, abundant functional groups (e.g. oxygen groups), and high porosity, and is widely used as an adsorbent in separation and purification processes.^1,2 However, due to the high cost of their production, these materials are considered more expensive than other adsorbents.³ Therefore, researchers have increased their efforts to identify more efficient precursors that are less expensive, environmentally friendly, and readily available for the production of AC. Biomass is a renewable carbon source and has many ecological advantages.⁴ Consequently, many lignocellulosic materials - including agricultural wastes and agro-industrial by-products, such as wood sawdust⁵, coconut shell⁶, Polygonum orientale L.⁷, yam peels¹, corncob⁸, and hazelnut bagasse⁹ - have been used as starting materials for the production of AC. Currently, most AC is mass-produced by chemical activation because of the high yield¹⁰, low activation time and temperature, single activation step, and well-developed pore structure¹¹. Chemically, AC is produced from various agricultural/industrial waste, including foxnut¹², tea industry waste¹³, grape seeds¹⁴, corncob¹⁵, kenaf core¹⁶, and coconut shell¹⁷. The palm oil tree is commonly grown all over the world, particularly in West Africa and Southeast Asia. In Malaysia, the industrial milling process and consumption of oil palms generates a large amount of waste that is not properly disposed of in the environment. Only 60% of the palm fibres and shells generated from this milling process are utilised as the boiler fuel in the mill to generate steam and electricity.¹⁸ Hence, there is an urgent need to reuse this material and reduce the amount for disposal.

An alternative to solving the disposal problems associated with agricultural waste is to increase the value of biomass through the preparation of adsorbent materials.¹⁹ Moreover, the main ecological problem in Malaysia is the pollution of water environments caused by rapid industrialisation and urbanisation.²⁰ Therefore, the conversion of palm kernel shells (PKS) into a value-added product (such as AC) serves not only as a cost-effective solid waste control measure for the palm oil industry, but can also be applied to water treatment. Fundamentally, the porous and adsorption properties of chemically prepared AC depend on the pyrolysis conditions and the type of precursors (preferably high-carbon, low-ash, high-availability and low-cost precursors)² and the activators used. Often chemical activation contributes to the porous structure and chemical properties of AC²¹ and many chemical activators, such as ZnCl₂²¹, KMnO₄²², H₃PO₄²³, KOH and K₂CO₃²⁴, have been used in the preparation of AC.

Lately, H₃PO₄ has received increasing attention as a high-performance activator for the preparation of porous carbon materials from different biomasses. This is because of the advantages of activation and biomass dehydration at lower temperature²⁵, inhibition of tar formation, and contribution to high surface area and desired porous structure. In addition, compared with other current activators, H₃PO₄ has the advantages of easy recycling and minimal environmental impact²⁶, making it one of the most attractive activators for carbon materials. For example, using H₃PO₄ at moderate temperature (350 °C), an AC with high surface area of 1547 m²/g was obtained from fir sawdust²⁷; also H₃PO₄ was used to produce AC from a Douglas fir with a high surface area of 826.4-1726.5 m²/g.²⁶ Similarly, a high surface area of 2806 m²/g was obtained by preparing AC by chemical activation of paulownia wood with H₃PO₄.²⁸ Therefore, H₃PO₄ is a potential activation candidate for enhancing the apparent surface area and porous structure of carbon materials. Thus, it is necessary to study the effect of H₃PO₄ on the carbonation of PKS. However, it can be challenging to improve the pore structure of PKS AC and enhance its adsorption performance without proper optimisation of the activator behaviour, and there are few reports in the literature on the H₃PO₄ activator behaviour of PKS.

Here we report on a low-cost method we have developed to produce high-quality porous carbon by preparing a series of ACs from PKS through H₃PO₄ treatment. We also investigated the effects of carbonisation temperature and H₃PO₄ ratio to obtain improved porous AC with enhanced adsorption performance. In addition, we performed proximate, apparent surface area, porosity, and microstructure analyses critical to understanding the properties of AC in PKS and its future applications. The ACs obtained were then applied in methylene blue and iodine removal from aqueous solution. Moreover, we aimed to promote the potential of PKS waste to address agricultural/industrial waste disposal issues and enhance its economic value. Waste that is not properly managed can have negative impacts on the environment. Burning waste in the open can cause air pollution and is particularly dangerous. Therefore, the valorisation of PKS also has environmental importance.

 

Materials and methods

Reagents

The main chemicals used in this study - namely phosphoric acid (H₃PO₄), NaOH and HCl - were purchased from Sigma-Aldrich. All chemicals were high purity and were prepared using deionised water. The PKS was supplied by the Malaysian Palm Oil Board.

Preparation of activated carbon

The PKS was washed with distilled water, dried in the sun, and crushed using a grinder (Hsiang Tai Machinery Industry Co.,Ltd.). PKS AC was prepared by chemical activation with 85% concentrated H₃PO₄. The H₃PO₄ and PKS powders were mixed in different ratios (1:1, 2:1, 1:2, and 3:1) of wt./wt., stirred intermittently by hand for 30 min, and then dried in an oven at 110 °C for 24 h. The samples were carbonised in a vertical tube furnace at predetermined temperatures (500 °C, 600 °C, and 700 °C) at a heating rate of 10 °C/min under a nitrogen flow of 20 mL/min for 1 h. The resulting AC was washed several times with warm deionised water until the pH was constant, then filtered and dried at 110 °C for 24 h. The yield of the AC obtained was calculated according to Equation 1. Figure 1 is a schematic of the adsorbent preparation.

 

 

 

Characterisation of adsorbents

The textural properties of the ACs were analysed with a surface area and porosity analyzer (Quanta Chrome Autosorb Automated Gas Sorption Instrument, Boynton Beach, FL, USA) at the temperature of liquid nitrogen. ACs were degassed under vacuum at 110 °C for 12 h before analysis. The BET (Brunauer-Emmet-Teller) equation was used to measure the specific surface area, and the pore distribution functions were determined from the adsorption branch of the isotherm according to the Barrett-Joyner-Halenda (BJH) model.²⁹ The surface morphology and elemental composition of the ACs were observed on a Field Emission Scanning Electron Microscope (FESEM, FEI Nova 230, Denton, TX, USA). Before the imaging, samples were mounted onto self-adhesive tape, in order to obtain good cross-sectional micrographs and avoid cross contamination, and then gold coated using an auto fine coater (JFC-1600, Akishima Japan) at 20 mA for 140 s to avoid charging. The elemental composition was studied by energy dispersive X-ray spectroscopy (DAX TEAM, USA), integrated with a high-resolution FESEM. The functional groups of the ACs were analysed by Fourier transform infrared spectroscopy (FTIR, Perkin-Elmer spectrum 100, Shelton, CT, USA) using the attenuated total reflectance sampling techniques. The dried AC samples were first ground into powder and then vacuum dried. With the help of a mechanical anvil, about 20 mg of each ground AC sample was mounted on the attenuated total reflectance crystal, and spectra were reported in the range of 4000 to 400 cm^-1 with a total of 32 scans per sample taken at a resolution of 4 cm^-1. The point of zero charge of the carbon materials was by pH drift method. A conical flask containing 100 mL of electrolyte solution (0.1 M NaCl) was maintained to a pH of 2, 4, 6, 8, or 10 with NaOH or HNO₃ solutions (0.1 M) using a pH meter. An amount of 0.1 g of the adsorbent was added to the flasks and the suspensions were agitated in a shaker bath for 24 h at 160 rpm (25±2 °C). After the preset time had elapsed, we decanted the equilibrated solution and recorded the final stabilised pH, then plotted the final recorded pH against the initial pH.

The porosity and adsorption tests

Aqueous adsorption tests were carried out on the produced ACs in order to assess their potential application in water treatment. Iodine and methylene blue (MB) were considered as probe molecules to represent a range of molecular sizes, i.e. for assessing the adsorption capacity of adsorbent pores for solutes of molecular sizes <10 Å (iodine) and >15 Å (MB)³⁰. For the method reported in Pam et al.²⁵ and Thitame and Shukla³¹, iodine (I₂) and MB were used respectively. The remaining MB concentrating in the filtrate was determined spectrometrically using a Perkin-Elmer Lambda 35 UV-vis spectrometer at 664 nm. The Langmuir model was applied to analyse the relationship between the equilibrium adsorption capacity of the MB on the activated carbon and its equilibrium solute solutions as expressed in Equation 2³²:

where K_L is the Langmuir constant (L/mg) and q_m is the maximum adsorption capacity (mg/g) relating to the monolayer covering of the adsorbate molecules.

The concentration of iodine in the solution (mg/g) is expressed by Equation 3:

Where M is the mass of the AC, the volumes of sodium thiosulfate used for titration of the blank and the tested sample are V_o and V_z, respectively, the concentration of the sodium thiosulfate solution is and 126. 92 is the mass of 1 mole of iodine.

All adsorption experiments were performed in duplicate.

 

Results and discussion

Elemental compositional and proximate analysis

The major elements on the surfaces of the carbons, as examined through energy-dispersive X-ray spectroscopy, revealed that the adsorbents consist primarily of elemental oxygen and carbon with small amounts of phosphorus. Results of the elemental compositional analysis are presented in Table 1.

 

 

As can be seen from Table 1, an increase in the proportion of H₃PO₄ led to an increase in the ash content. This observation is similar to that of Anisuzzaman et al.³³ who attributed the leftover ash in the AC to trapped dehydrated H₃PO₄ products. In addition to this, a decrease in moisture percentage from 12% to 6% can be seen as carbonisation temperature increased from 500 °C to 700 °C; however, the impregnation ratio had no substantial effect on the moisture percentage. The decrease in the moisture content with increasing reaction temperature is due to the elimination of water molecules at higher temperature.

Basic properties

Point of zero charge (pH_pzc) refers to the point at which the surface charge density generated on the surface of the adsorbent is zero. The examination of pH_pzc offers an insight into the specificity of adsorption.³⁴ Figure 2a represents the plot of initial and final pH values and the pH_pzc is the point at which the curve of pH final vs pH initial intersects the line pH_initial pH_final.³⁵ The pH_pzc values of ACs are concentrated in the range of 2-4.5, which indicates that the surface of the ACs are acidic and shows a clear correlation with the surface chemistry of ACs obtained from FTIR; such a character demonstrates good potential for the elimination of metals from contaminated water. Generally, the charges on the surface can be -YOH₂⁺ or -YOH, or -YO^-, which represents the protonated, neutral, and deprotonated sites on the surfaces of the ACs, respectively. If the pH value of the adjacent solute is lower than -YOH, the carbon material is positively charged (due to migration of the neighbouring H⁺ to the oxygen radical of AC) and more anions are adsorbed. However, a pH of the surrounding solute above -YOH introduces negatively charged surfaces (due to breaking H⁺ bonds in OH or COOH which exposes negative oxygen ions) promoting the removal of cations in aqueous solution. pH_PZC is the point where -YOH₂⁺ and -YO^- are equal to zero. In generally, ACs with more oxygen-containing functional groups show lower pH_PZC.³⁶

 

 

Results of the FTIR analysis of the ACs are shown in Figure 2b. The FTIR spectra for AC-700 2:1, AC-600 3:1, AC-600 2:1, AC-600 1:1, AC-500 2:1 and AC-500 1:1 have peaks that were observed in the regions 1158, 1180, 3248, 2900, 1742 and 1061 cm^-1, conforming to a P=O bond in phosphate ester, O-C bond (in P-O-C linkage or P=OOH bond), OH stretch, CH, C=O and C-O, respectively.^37-40 The FTIR peaks have similar patterns and related functional groups, which can be attributed to the same precursors deployed. No major differences were observed in the peaks when varying the H₃PO₄ concentration. Similar spectral results were also observed for AC prepared from rice husks.⁴¹

The surface morphologies of various ACs observed by FESEM are shown in Figure 3. The average degree of porosity strongly depends on the concentration of the impregnation agent.³³ Obviously, AC-500 (Figure 3a-b) and AC-600 1:2 (Figure 3d) showed very limited and poorly developed pore structure. Figure 3c-d shows that, as the impregnation concentration increased from 1 (AC-600 1:1) to 2 (AC-600 2:1), the morphology of the pore increased. The surface structure of AC-600 2:1 showed cleaner and burnout pores with tunnel-like structures or cavities (Figure 3e), as confirmed by the BET result (Table 2). AC-600 1:1 and AC-600 3:1 showed typical cauliflower-like structural morphology, while AC-600 1:2 (Figure 3d) showed loaf-shaped, ellipsoidal aggregated pellets.

 

 

The development of the pore structure can be traced to the decomposition of the lignocellulosic structure in PKS due to the activity of H₃PO₄ and thermal expansion during carbonisation. During the carbonisation process, the presence of H₃PO₄ promotes pyrolysis dehydration, the decomposition of lignocellulosic materials and the formation of cross-linked structures, which promote the development of pores.²⁸ This was reasonable enough, because increasing the proportion of H₃PO₄ would activate the carbon and increase the volatile loss of the biopolymer, and bring about a greatly improved pore volume and surface area. However, a negative trend in pore development was observed at acid ratio 3 (at 600 °C), while the surface structure of the AC sample showed unclear pores (Figure 3f). This finding may be because the pores in the sample were blocked by H₃PO₄, which led to the destruction of the morphological structure of the AC. Furthermore, addition of H₃PO₄ beyond the optimum degree of impregnation may result in an insulating layer covering the particles, which may reduce the activation process.³³ This may reduce the BET surface area and average pore size observed in this sample. In addition, when the temperature was increased to 700° C (Figure 3g-h), the pore morphology was reduced due to destruction of the morphological structure, thereby reducing the space between the pores at higher temperature.⁴²

The details of the pore size distribution of the ACs are shown in Table 2. According to the IUPAC classification, the reported isotherm is a typical IV-type isotherm, supplemented by an H4 hysteresis loop, which is well known for micro-mesoporous carbon. AC-500 2:2, AC-600 2:1, AC-600 1:1 and AC-700 2:1 have obvious adsorption at low p/p^o, and there is a slight hysteresis, suggesting that micropores are filled and mesopores are affected by limit. The pore structure of AC measured by the BJH method is predominately microporous, concentrated around 1.50-2.50 nm (Figure 4c-d).

 

 

From the results, the heat treatment and the acid/precursor weight ratio affected the BET surface area, pore volume and micropore size. At all carbonisation temperatures (500-700 °C), as the ratio of acid to PKS increased, the total pore volume increased, and the impregnation rate had a significant effect on the total pore volume. The textural properties of the prepared ACs were compared with those of previous agricultural waste based ACs and commercially available ACs. The apparent surface area of 1560 m²/g is very high and is in the comparable range of carbon (500-1500 m²/g) associated with commercial biomass AC.⁶ The corresponding maximum specific surface area of 1560 m²/g is much larger than that of ACs prepared from rice husk (750 m²/g) and bagasse (674 m²/g).⁴³ The specific surface area of the AC was also larger than or equal to those reported from Yam peels (715 m²/g)¹, sugarcane bagasse (1132 m²/g)⁴⁴, peanut shells (1642 m²/g)⁴⁵, and jackfruit peel (1260 m²/g)⁴⁶, suggesting that the AC prepared from PKS is a promising adsorbent. Also, the highest pore volume of 0.611 cm³/g in the current study is correspondingly larger than those of the commercial AC, i.e. 0.172, 0.369, and 0.250 cm³/g for BPL⁴⁷, and 0.60 and 0.52 cm³/g for PCB (Calgon Carbon Co., Pittsburgh, USA)⁴⁸. It is well known that phosphoric acid can produce AC with inherent nuances in pore structure and a high proportion of micropores and mesopores. This may explain the satisfactory high-quality AC with an improved microstructure reported in this work.

Effects of process parameters on AC yield, BET surface area and pore properties

Product yield is an important measure for evaluating the feasibility of an adsorbent from a given precursor.⁴⁹ As shown in Table 2, the percentage yields ranged from 23.4% to 53.6% and were observed to decrease with increasing acid/PKS ratio and activation temperature (500-700 °C). The H₃PO₄ impregnation decreased the yield percentage of AC due to the increased removal of char.⁵⁰ Chen et al.⁵¹ explained that at high H₃PO₄ content, the gasification of surface carbon atoms became predominant, resulting in an increase in the weight loss and a low carbon yield. This trend is consistent with the findings of Al Bahri et al.⁵²

Temperature had a significant effect on the activation yield; increasing the temperature from 500 °C to 600 °C decreased the yield from 55.5% to 30.7%. The reason for this is that, at a higher carbonisation temperature, more acid and/or volatile substances will evaporate from the sample, thereby reducing the carbon yield.⁵⁰ Yefremova et al.⁵³ proposed that the decrease in the yield of carbonised products at higher pyrolysis temperatures may be due to the increase in the primary decomposition of the precursor and the increase in the secondary decomposition of the formed carbon material. Mussatto et al.⁴⁹, Hayashia et al.⁵⁴ and Wu et al.⁵⁵ reported similar results from biomass materials. The effects of temperature and chemical ratio on BET surface area and average pore volume are shown in Table 2. As the activation temperature was increased from 500 °C to 700 °C, the surface area was observed to increase at a relatively low value of 961 m²/g, reaching a maximum value of 1560 m²/g at 600 °C, and then reduced reasonably to 875.8 m²/g at 700 °C. The decrease in the surface area at 700 °C may be due to the fact that the elastic limit and volume shrinkage at high temperatures make the acid habitually sedentary to support more pore development.⁵⁶ The impregnation rate has a significant effect on the total pore volume, because the total pore volume increases rapidly with the increase of the acid/PKS ratio, regardless of the carbonisation temperature. The BET surface area and the average pore width (nm) of the ACs, respectively, increased from 961 m²/g and 1.53 nm to 1560 m²/g and 1.71 nm as the impregnation ratio increased from 1 to 2. This is because the increase in H₃PO₄ promotes the contact area between PKS and H₃PO₄, which increases the diffusion of H₃PO₄ into the pore structure which increases the porosity of the final product. The BET surface area and average pore width were then reduced to 1266 m²/g and 1.53 nm, respectively, at ratio 3. This is because the higher phosphoric acid concentration forms a protective layer that prevents the incorporation of the activator into the sample, thereby preventing any increase in the specific surface area and total pore volume.⁵¹ However, when the ratio (H₃PO₄/PKS) was reduced to 1:2, the total pore volume was significantly reduced to a minimum value of 0.02 cm³/g. This could be due to an insufficient amount of H₃PO₄, which could not activate the sample effectively.³⁹ Similar behaviour has also been reported for the effect of the impregnation ratio on the porosity of ACs obtained by H₃PO₄ activation of other biomass.^46,57 Compared to other ratios, the AC produced at 2:1 H₃PO₄ showed the strongest pore width of 1.71 nm. It can be concluded that an acid/precursor ratio of 2:1 is suitable for the formation of useful pore structures and that maintaining this ratio can lead to favorable development of porosity in ACs. The effects of carbonisation temperature and impregnation ratio on BET surface area are summarised in Figure 5.

 

 

Adsorptive properties of the AC produced

The experimental data on MB and I₂ adsorption are shown in Figure 6. The data show that the MB adsorption capacity and iodine value of AC are significantly affected by the activator ratio and temperature. We report an adsorption capacity of 118-358 mg/g for MB, while that for I₂ was between 235.8 mg I₂/g and 781.7 mg I₂/g. The values obtained were higher than 1.33 mg/g and 769 mg/g reported by Aygün et al.⁵⁸ and Gong et al.³² for MB adsorption, respectively.

 

 

We found a positive correlation between the I₂ value and average pore volume. Notably, AC-600 2:1, with the highest average pore width (1.71 nm), also had the highest iodine value at 781.7 mg I₂/g carbon. A sudden increase in iodine value was observed as the carbonisation temperature increased from 500 °C to 600 °C, but decrease at 700 °C, which could be caused by a reduction in the carbon framework at higher temperature, which is due to shrinkage in the carbon structure at higher temperature. Similar assertions were made in related research by Mopoung and Preechachan⁵⁹. The higher iodine value depends on the structural properties of the adsorbent; the MB value is lower and consistent with the limited mesopore width, as shown in Figure 4a-d. Consequently, during the diffusion process, because the cross-section of the pores is too small, the MB cannot enter the pores, which may lead to pore blockage. Another important consideration is that the presence of surface oxygen complexes may increase the resistance of MB molecules to diffusion in carbon pores.⁶⁰ Therefore, this suggests that AC can adsorb more small molecules (such as iodine) and may not be suitable for adsorbing macromolecules such as MB.

Adsorption mechanism of methylene blue dye

The driving factors of the adsorption of the MB dye from aqueous solution onto the AC have been classified as electrostatic interaction, hydrogen bonding, π-π interaction and pore filling. According to the available functional groups (carboxyl, hydroxyl, and carbonyl) on the surface of the ACs as buttressed by the FTIR spectral results, there are possible electrostatic interactions between the negatively charged functional groups on the AC surface and the positively charged species of the MB (Figure 7a). Hydrogen bonding is also a potential adsorption mechanism. The nitrogen atoms on the adsorbate MB could generate hydrogen bonding with the oxygen atoms available on the surface of the ACs, as sketched in Figure 7b. In addition, MB molecules can be easily adsorbed by the π-π stacking interaction between the aromatic backbone of MB molecules and the graphene framework of the ACs (Figure 7c). Additionally, pore filling can take place due to the porous nature of the adsorbent with acceptable pore volume, thus pore filling is considered a potential mechanism (Figure 7d). However, MB as a high-molecular-weight dye may have difficulty accessing the inner pores of the AC samples, which reduces its adsorptive capacity in comparison to iodine, as reported earlier in this work. The probable MB adsorption mechanism onto the ACs is schematically illustrated in Figure 7.

 

 

Conclusion

The present findings demonstrate the efficacy of using PKS to prepare high-porosity ACs via H₃PO₄ activation. The isotherm of the prepared AC was type IV. Increasing the acid ratio from 1 to 2 increased the BET surface area from 961 to 1560, but showed a negative trend at ratio 3. Increasing the acid ratio increased the total pore volume of the AC suddenly; however, the pore diameter showed no significant change. At optimal conditions, the AC (AC-600 2:1) produced at an acid to precursor ratio of 2:1 and carbonation temperature of 600 °C, showed the highest apparent BET surface area and total pore volume. The adsorption potential of the ACs in aqueous solutions containing methylene blue and iodine was promising, and further demonstrated the biosorbent potential in water purification. The physicochemical properties of H₃PO₄-treated PKS AC was far better than those of other agricultural-based and commercially available AC. This method may provide a new alternative strategy to produce low-cost AC and manage PKS waste without burning or throwing it into waterways.

 

Competing interests

We have no competing interests to declare.

 

Authors' contributions

A.A.P.: Methodology; investigation; project administration; review and editing; writing - original draft; reviewing and editing. A.H.A.: Supervision; writing - review and editing; project leadership; project management. Y.P.T.: Supervision; writing - review and editing; project management. Z.Z.: Supervision; writing - review and editing; project administration; project management.

 

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Correspondence:
Aloysius Pam
Email: aloysius.pam@fulokoja.edu.ng

Received: 23 Mar. 2022
Revised: 24 June 2022
Accepted: 24 June 2022
Published: 29 Sep. 2022

 

 

Editors: Priscilla Baker, Amanda-Lee Manicum
Funding: None