Servicios Personalizados
Articulo
Indicadores
Links relacionados
- Citado por Google
- Similares en Google
Compartir
Journal of the Southern African Institute of Mining and Metallurgy
versión On-line ISSN 2411-9717
versión impresa ISSN 2225-6253
Resumen
VOS, C.F.; DAVIDTZ, J.C. y MILLER, J.D.. The effect of nC12-trithiocarbonate on pyrrhotite hydrophobicity and PGE flotation. J. S. Afr. Inst. Min. Metall. [online]. 2018, vol.118, n.10, pp.1095-1102. ISSN 2411-9717. http://dx.doi.org/10.17159/2411-9717/2018/v118n10a11.
This work presents the potential for improving the flotation recovery of slow-floating sulphide minerals with the use of starvation dosages of a normal dodecyl (n-C12) trithiocarbonate (TTC) co-collector, together with a sodium isobutyl xanthate (SiBX) and dithiophosphate (DTP) collector mixture. At potentials below -150 mV (SHE), addition of nC12-TTC with SiBX improves the hydrophobicity of pyrrhotite, yielding captive bubble contact angles greater than those measured for SiBX or nC12-TTC alone, suggesting a low potential synergistic effect. This synergistic effect is further studied using Fourier transform infrared (FTIR) spectroscopy, the results indicating an increase in the surface concentration of the collector species when in a mixture. Thus, nC12-TTC with SiBX may act as an immobile surface anchor to which SiBX/SiBX2 molecules bond, increasing the localized concentration of collector species. Bench-scale flotation tests using mixtures of SiBX/DTP/nC12-TTC on a platinum group element (PGE)-bearing ore from the Bushveld Complex in South Africa confirm an improved metallurgical performance at very low substitutions (approx. 5 molar per cent) of SiBX. The improved recoveries for PGE, Cu, and Ni are correlated with improvements in the flotation kinetics of their slow-floating components.
Palabras clave : sulphide flotation; hydrophobicity; collector; nC12-trithiocarbonate; synergistic effect.