SHORT COMMUNICATION

A convenient and direct route to 1,2-dichlorovinylphosphine oxides via copper-catalyzed addition of H-phosphine oxides to 1,2-dichloroethyne

Xiang-Zhu Zhang^I; Jing-Ya Ma^II; Ming-shu Wu^{I, II, *}

^IInstitute of Green Chemistry, Anyang Institute of Technology, Anyang, Henan 455000, People's Republic of China
^IICollege of Chemistry & Chemical Engineering, Hainan Normal University, Haikou, 571158, People's Republic of China

ABSTRACT

An efficient, convenient and inexpensive CuI-catalyzed method for the synthesis of 1,2-dichlorovinylphosphine oxides from substituted phosphites, diphenylphosphine oxide and 1,2-dichloroethyne has been developed in moderate-good yields, and the reactions provided mainly regioselective anti addition products.

Keywords: Copper-catalyzed addition reaction, 1,2-dichlorovinylphosphine oxides

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Acknowledgement

This work was supported financially by the National Natural Science Foundation of China (No.21162008).

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Received 8 July 2012
Revised 30 August
Accepted 1 October 2012

* To whom correspondence should be addressed. E-mail: wumingshu@126.com